( Neelam )
Sapphire
Sapphire is the non red variety of the mineral corundum, an aluminium oxide (Al2O3). It can be found naturally or manufactured in large crystal boules for varied applications, including infrared optical components, watch faces, high-durability windows, and wafers for the deposition of semiconductors such as GaN nanorods.
The mineral corundum consists of pure aluminium oxide. Trace amounts of other elements such as iron, titanium and chromium give corundum their blue, yellow, pink, purple, orange or greenish color. Sapphire includes any gemstone quality varieties of the mineral corundum except the fully saturated red variety, which is instead known as ruby, and the pinkish-orange variety known as padparadscha.
Various shades of blue, dark and light, result from titanium and iron substitutions in the aluminium oxide crystal lattice. Some stones are not well saturated and show tones of gray. It is common practice to bake natural sapphires to improve or enhance color. This is usually done by heating the sapphires to temperatures of up to 1800°C for several hours, or by heating in a nitrogen deficient atmosphere oven for seven days or more. On magnification, the silk due to included rutile needles are often visible. If the needles are unbroken, then the stone was not heated; if the silk is not visible then the stone was heated adequately. If the silk is partially broken, then a process known as low tube heat may have been used. Low tube heat is the process whereby the rough stone is heated to 1300 °C over charcoal for 20 to 30 minutes. This removes gray or brown in the stone and improves color saturation.
Although blue is considered the normal color for sapphires, they can be found across a full range of spectral colors as well as brown, colorless, grey and black. Those other than blue in color are considered fancy color sapphires. Some natural sapphires can be found as completely transparent, or "white." White sapphires usually come out of the ground as light grey or brown and are then heated to make them clear. However, in very rare circumstances they will be found in a clear state.