( Pukhraaj )
Sapphire
Sapphire is the non red variety of the mineral corundum, an aluminium oxide (Al2O3). It can be found naturally or manufactured in large crystal boules for varied applications, including infrared optical components, watch faces, high-durability windows, and wafers for the deposition of semiconductors such as GaN nanorods.
The mineral corundum consists of pure aluminium oxide. Trace amounts of other elements such as iron, titanium and chromium give corundum their blue, yellow, pink, purple, orange or greenish color. Sapphire includes any gemstone quality varieties of the mineral corundum except the fully saturated red variety, which is instead known as ruby, and the pinkish-orange variety known as padparadscha.
Although blue is considered the normal color for sapphires, they can be found across a full range of spectral colors as well as brown, colorless, grey and black. Those other than blue in color are considered fancy color sapphires. Some natural sapphires can be found as completely transparent, or "white." White sapphires usually come out of the ground as light grey or brown and are then heated to make them clear. However, in very rare circumstances they will be found in a clear state.
Fancy Color Sapphire
Purple sapphires are lower in price than blue ones. These stones contain the trace element vanadium and come in a variety of shades. Yellow and green sapphires have traces of iron that gives them their color. Pink sapphires have a trace of the element chromium and the deeper the color pink the higher their monetary value as long as the color is going toward the red of rubies. Sapphires also occur in shades of orange and brown, and colorless sapphires are sometimes used as diamond substitutes in jewelry. Salmon-color padparadscha sapphires are orangy-pink, pinkish-orange or pink-orange in color, which often fetch higher prices than many of even the finest blue sapphires. The word 'padparadscha' is Sinhalese for 'lotus flower'. Recently many sapphires of this color have appeared on the market as a result of a new treatment method called "bulk diffusion".
Color shift sapphires are blue in outdoor light and purple under [incandescent] indoor light. Color changes may also be pink in daylight to greenish under fluorescent light. Some stones shift color well and others only partially, in that some stones go from blue to bluish purple. Such color-change sapphires are widely sold as “lab” or “synthetic” alexandrite, which is accurately called an alexandrite simulant since the latter is actually a type of chrysoberyl---an entirely different substance whose pleochroism is different and much more pronounced than color-change corundum (sapphire).
A star sapphire is a type of sapphire that exhibits a star-like phenomenon known as asterism . Star sapphires contain intersecting needle-like inclusions (often the mineral rutile) that cause the appearance of a six-rayed 'star'-shaped pattern when viewed with a single overhead light source. The value of a star sapphire depends not only on the carat weight of the stone but also the body color, visibility and intensity of the asterism.
Some sapphires are heat-treated or otherwise enhanced to improve their appearance and color, though some people object to such practices and prefer natural untreated stones. Heat treatments tend to improve the sapphire's color and clarity, and it is unusual to find un-heated stones for sale. Diffusion treatments are somewhat more controversial as they are used to add elements to the sapphire for the purpose of improving color and thus enhancing the stone's value. Heat treatment is usually detectable by microscopic analysis, but diffusion isn't always detectable.